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- W4235992550 abstract "An adiabatic solution calorimeter was used for measuring enthalpies of solution in water of seven samples of cytosine for which analytical data are given. Our best values are: ΔH∘(∞,298.15K)=(27.2±4.0)kJ⋅mol-1, and ΔCp=(76±21)J⋅mol-1⋅K-1,298K<T<324Kat(24±2)mmol⋅kg-1. Evidence is given for an unidentified side reaction at low concentrations which is responsible for the large uncertainty assigned to the enthalpy of solution at infinite dilution. An approximate value of (1.44 ± 0.08) g · mL-1 for the density of cytosine was also measured. Values are calculated for ΔG° and ΔS° for the solution reaction." @default.
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- W4235992550 date "1978-11-01" @default.
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- W4235992550 title "Enthalpies of solution of the nucleic acid bases. 3. Cytosine in water" @default.
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- W4235992550 doi "https://doi.org/10.6028/jres.083.035" @default.
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