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- W4236037899 abstract "Abstract The hardness of oxo ions (O 2− ) means that coinage‐metal (Cu, Ag, Au) clusters supported by oxo ions (O 2− ) are rare. Herein, a novel μ 4 ‐oxo supported all‐alkynyl‐protected silver(I)–copper(I) nanocluster [Ag 74− x Cu x O 12 (PhC≡C) 50 ] ( NC‐1 , avg. x =37.9) is characterized. NC‐1 is the highest nuclearity silver–copper heterometallic cluster and contains an unprecedented twelve interstitial μ 4 ‐oxo ions. The oxo ions originate from the reduction of nitrate ions by NaBH 4 . The oxo ions induce the hierarchical aggregation of Cu I and Ag I ions in the cluster, forming the unique regioselective distribution of two different metal ions. The anisotropic ligand coverage on the surface is caused by the jigsaw‐puzzle‐like cluster packing incorporating rare intermolecular C−H⋅⋅⋅metal agostic interactions and solvent molecules. This work not only reveals a new category of high‐nuclearity coinage‐metal clusters but shows the special clustering effect of oxo ions in the assembly of coinage‐metal clusters." @default.
- W4236037899 created "2022-05-12" @default.
- W4236037899 creator A5004909625 @default.
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- W4236037899 date "2019-07-30" @default.
- W4236037899 modified "2023-09-30" @default.
- W4236037899 title "An All‐Alkynyl Protected 74‐Nuclei Silver(I)–Copper(I)‐Oxo Nanocluster: Oxo‐Induced Hierarchical Bimetal Aggregation and Anisotropic Surface Ligand Orientation" @default.
- W4236037899 cites W1973036992 @default.
- W4236037899 cites W1973544071 @default.
- W4236037899 cites W1978007782 @default.
- W4236037899 cites W1981448282 @default.
- W4236037899 cites W1989296786 @default.
- W4236037899 cites W1995675262 @default.
- W4236037899 cites W2002578376 @default.
- W4236037899 cites W2007407498 @default.
- W4236037899 cites W2014316343 @default.
- W4236037899 cites W2020501424 @default.
- W4236037899 cites W2023905744 @default.
- W4236037899 cites W2024175762 @default.
- W4236037899 cites W2028035263 @default.
- W4236037899 cites W2030913016 @default.
- W4236037899 cites W2031164685 @default.
- W4236037899 cites W2035299445 @default.
- W4236037899 cites W2052979701 @default.
- W4236037899 cites W2062202346 @default.
- W4236037899 cites W2066920637 @default.
- W4236037899 cites W2071202770 @default.
- W4236037899 cites W2071366579 @default.
- W4236037899 cites W2072594364 @default.
- W4236037899 cites W2074257209 @default.
- W4236037899 cites W2082591597 @default.
- W4236037899 cites W2101239190 @default.
- W4236037899 cites W2101741054 @default.
- W4236037899 cites W2115097441 @default.
- W4236037899 cites W2129612320 @default.
- W4236037899 cites W2136393782 @default.
- W4236037899 cites W2137689493 @default.
- W4236037899 cites W2159727854 @default.
- W4236037899 cites W2274551438 @default.
- W4236037899 cites W2276525825 @default.
- W4236037899 cites W2285097822 @default.
- W4236037899 cites W2315871585 @default.
- W4236037899 cites W2318247405 @default.
- W4236037899 cites W2318371622 @default.
- W4236037899 cites W2318671082 @default.
- W4236037899 cites W2318773385 @default.
- W4236037899 cites W2334515515 @default.
- W4236037899 cites W2336591373 @default.
- W4236037899 cites W2515105890 @default.
- W4236037899 cites W2515286324 @default.
- W4236037899 cites W2519276590 @default.
- W4236037899 cites W2527048096 @default.
- W4236037899 cites W2531912491 @default.
- W4236037899 cites W2535515805 @default.
- W4236037899 cites W2559214744 @default.
- W4236037899 cites W2567271618 @default.
- W4236037899 cites W2588265396 @default.
- W4236037899 cites W2602528341 @default.
- W4236037899 cites W2619463084 @default.
- W4236037899 cites W2623026738 @default.
- W4236037899 cites W2626561978 @default.
- W4236037899 cites W2740951640 @default.
- W4236037899 cites W2742341008 @default.
- W4236037899 cites W2765181213 @default.
- W4236037899 cites W2765374420 @default.
- W4236037899 cites W2778959544 @default.
- W4236037899 cites W2782747403 @default.
- W4236037899 cites W2788676263 @default.
- W4236037899 cites W2793806321 @default.
- W4236037899 cites W2795578707 @default.
- W4236037899 cites W2805948546 @default.
- W4236037899 cites W2808467654 @default.
- W4236037899 cites W2883415957 @default.
- W4236037899 cites W2886873440 @default.
- W4236037899 cites W2895904886 @default.
- W4236037899 cites W2897354486 @default.
- W4236037899 cites W2910376802 @default.
- W4236037899 cites W2917753515 @default.
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- W4236037899 cites W2953008588 @default.
- W4236037899 cites W4229507839 @default.
- W4236037899 cites W4233017345 @default.
- W4236037899 cites W4237116817 @default.
- W4236037899 cites W4238646879 @default.
- W4236037899 cites W4245060413 @default.
- W4236037899 doi "https://doi.org/10.1002/ange.201906538" @default.
- W4236037899 hasPublicationYear "2019" @default.
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