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- W4236039675 abstract "Abstract A rigid naphthalenediamine framework has been used to prepare antimony hydrides that feature LUMO shapes and energies similar to those found in secondary boranes. By exploiting this feature, we introduce the first examples of uncatalyzed hydrostibination reactions of robust C≡C, C=C, C=O, and N=N bonds as new elementary hydrometalation reactions analogous to hydroboration. These results endorse the notion of a diagonal relationship between the lightest p‐block element and the heaviest Group 15 elements and may lead to the conception of novel reaction chemistry." @default.
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- W4236039675 date "2019-10-24" @default.
- W4236039675 modified "2023-10-02" @default.
- W4236039675 title "Hydrostibination" @default.
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- W4236039675 doi "https://doi.org/10.1002/ange.201911842" @default.
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