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- W4236062502 abstract "Getting on with the neighbors: The Poisson–Boltzmann equation has for decades been a keystone in the theoretical description of the electric double layer of colloids. However, there are some fascinating phenomena that challenge this traditional approach, such as overcharging, which can come about for highly charged macroions in the presence of multivalent counterions. Why does the classical picture fail under such conditions? The figure illustrates the quantitative and qualitative differences that can be found for the macroion–ion radial distribution functions predicted by the Poisson–Boltzmann theory (••••) and a modern integral equation theory (—)." @default.
- W4236062502 created "2022-05-12" @default.
- W4236062502 date "2003-03-17" @default.
- W4236062502 modified "2023-09-27" @default.
- W4236062502 doi "https://doi.org/10.1002/cphc.v4:3" @default.
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