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- W4236074331 abstract "Reactions of N-phenyl-S-methyldithiocarbamate (L 1 ) and N,N-dimethyl-S-methyldithio-carbamate (L 2 ) with CuCl 2 , [Cu 2 I 2 (PPh 3 ) 3 ] and HAuCl 4 yield the complexes [CuCl(L 1 ) 3 ] • CH 2 Cl 2 (1), [AuCl(L 1 ) 2 ] (2), [CuI(L 1 )(PPh 3 )] 2 (3) and [Cu 2 I Cu II Cl 4 (L 2 ) 2 ] n (4). Their structures have been determined by single crystal X-ray crystallography. 1 and 2 are monomeric, with Cu(I) tetrahedrally four-coordinate and Au(I) two-coordinate with an S-Au-S angle of 158.2(1)°. 3 is dimeric with a central CuI 2 Cu core, the Cu•••Cu distance of which [314.9(1) pm] is rather large. The mixed valence complex 4 has a chain structure with the identity period Cu II (μ-Cl) 2 Cu I (μ-S) 2 Cu I (μ-Cl) 2 . Cu I is in a tetrahedral, Cu II in a square planar environment. The (μ-S) 2 bridged Cu I ••• Cu I distance is only 259.1(1) pm. The structures of the CuX 2 Cu cores of 3 and 4 are mainly determined by steric interactions of the donor atoms within the coordination spheres of the metal centers." @default.
- W4236074331 created "2022-05-12" @default.
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- W4236074331 date "1993-09-01" @default.
- W4236074331 modified "2023-09-25" @default.
- W4236074331 title "Kupfer- und Goldkomplexe von Dithiocarbaminsäureestern. Strukturen von [CuCI(L1)3] · CH2Cl2, [AuCl(L1)2], [CuI(L1)(PPh3)]2 und [Cu2 ICuIICl4(L2)2]n (L1 = N-Phenyl-S-methyldithiocarbaminsäureester, L2 = N,N-Dimethyl-S-methyldithiocarbaminsäureester) / Copper and Gold Complexes of Dithiocarbamate Esters. X-Ray Structures of [CuCl(L1)3] · CH2Cl2, [AuCl(L1)2], [CuI(L1)(PPh3)]2 and [Cu2 ICuIICl4(L2)2]n (L1 = N-Phenyl-S-methyldithiocarbamate, L2 = N,N-Dimethyl-S-methyldithiocarbamate)" @default.
- W4236074331 doi "https://doi.org/10.1515/znb-1993-0911" @default.
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