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- W4236098498 abstract "Polycyclic tetraphosphorus compounds, including the P4 molecule, its oxides, sulfides, imides and mixed derivatives, and related compounds, offer a wide choice of potential donor sites. Their coordination chemistry is described and discussed. The transmission of structural and electronic effects through the molecular frame -i.e. the interdependence of the phosphorus donor sites - is evident in their chemical behavior, kinetic and thermodynamic differences, spectral and structural data. The interpretation of NMR and X-ray data in terms of changes in electronic distribution and of π character in bonding, is critically scrutinized. It is concluded that apportioning the observed effects among σ and π electronic contributions and steric contributions can usually not be achieved in a reliable way. Structural softness and disorder in the solid are recognized as prominent features characteristic of tetraphosphorus closo-compounds. The field contains many riddles, and promises new developments, especially in the realm of mixed picnogen/transition metal complexes and clusters." @default.
- W4236098498 created "2022-05-12" @default.
- W4236098498 creator A5009823499 @default.
- W4236098498 date "1983-09-30" @default.
- W4236098498 modified "2023-09-25" @default.
- W4236098498 title "Coordination and Related Chemistry of Polycyclic Tetraphosphorus Compounds" @default.
- W4236098498 doi "https://doi.org/10.1021/bk-1983-0232.ch002" @default.
- W4236098498 hasPublicationYear "1983" @default.
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