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- W4236100713 abstract "Abstract The asymmetric rhodium‐catalyzed alkenylation of enones and imines with arylboronic acids has been developed. A highly controllable aryl to vinyl 1,4‐rhodium migration is the key step. Stereodefined vinyl moieties were installed in excellent enantioselectivies for most examined examples. DFT calculations reveal that the driving force of this rhodium migration is a kinetically favored process." @default.
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- W4236100713 date "2019-02-04" @default.
- W4236100713 modified "2023-10-14" @default.
- W4236100713 title "Asymmetric Alkenylation of Enones and Imines Enabled by A Highly Efficient Aryl to Vinyl 1,4-Rhodium Migration" @default.
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- W4236100713 doi "https://doi.org/10.1002/ange.201813585" @default.
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