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• W4236273146 abstract "Abstract An efficient pincer‐ligand‐based cobalt‐complex‐catalyzed allene hydroboration affording Z ‐allylic boronates is described. The reaction demonstrates an excellent regio‐ as well as Z ‐stereoselectivity and a wide substrate scope that tolerates many functional groups. Based on solvent‐assisted electrospray ionization mass spectrometry (SAESI‐MS) studies, a rationale for the cobalt‐catalyzed hydroboration involving the highly selective insertion of an allene into the Co−H bond to form Z ‐allylic cobalt intermediates is proposed." @default.
• W4236273146 created "2022-05-12" @default.
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• W4236273146 date "2020-02-18" @default.
• W4236273146 modified "2023-10-16" @default.
• W4236273146 title "Cobalt‐Catalyzed Regio‐ and Stereoselective Hydroboration of Allenes" @default.
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• W4236273146 doi "https://doi.org/10.1002/ange.201915716" @default.
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