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- W4236385729 abstract "2,3-Dicarboxyaniline in its anionic state is oxidatively polymerized in aqueous solution by Na2S2O8 as an oxidant to yield oligo(2,3-dicarboxyaniline) as a novel oligoaniline. XPS analysis reveals that the structure of the resulting oligomer is 61% quinoid and 39% benzenoid with ca. 21% self-doping degree. The resulting oligoaniline shows two stable redox couples over a wide pH range on the electrode. Both redox processes involve 1 electron transfer with 1 proton transfer in each 2 monomer units, a redox chemistry that is quite distinct from conventional polyaniline. The redox activity of the resulting polymer in pseudo-neutral conditions is caused by the carboxy group with high density which acts as a proton source for the protonation on the nitrogen atom of the polyaniline chain." @default.
- W4236385729 created "2022-05-12" @default.
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- W4236385729 date "2000-01-01" @default.
- W4236385729 modified "2023-09-26" @default.
- W4236385729 title "A self-doped oligoaniline with two stable redox couples in a wide pH range" @default.
- W4236385729 doi "https://doi.org/10.1002/(sici)1521-3935(20000101)201:1<6::aid-macp6>3.3.co;2-v" @default.
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