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- W4236474588 abstract "Der starke innere Druck auf das Sr-Ion im neuartigen Perowskit SrCu3Fe4O12 (siehe Struktur) führt zu einer riesigen negativen thermischen Ausdehnung (NTE) zwischen 170 und 270 K. Laut Mößbauer-Spektroskopie tritt unter 200 K eine Ladungsdisproportionierung von FeIV in FeIII und FeV auf. Somit kann der isoelektrische Austausch von A-Stellen-Kationen eine drastische Änderung von elektronischen und Struktureigenschaften in ACu3Fe4O12-Perowskiten auslösen. Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article." @default.
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- W4236474588 date "2011-06-06" @default.
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- W4236474588 title "Giant Negative Thermal Expansion in the Iron Perovskite SrCu3Fe4O12" @default.
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- W4236474588 doi "https://doi.org/10.1002/ange.201102228" @default.
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