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- W4236525260 abstract "The stereoselective synthesis of α-allenols is described. The authors show that arylboronic acids as well as MeMgCl fare well as nucleophiles. A variety of alkynyl oxiranes are suitable giving the syn-configured α-allenols. The reaction proceeds through a SN2′-type mechanism. Coordination of the rhodium with the oxirane oxygen is believed to be a reason for the observed high diastereoselectivity." @default.
- W4236525260 created "2022-05-12" @default.
- W4236525260 date "2007-11-22" @default.
- W4236525260 modified "2023-10-18" @default.
- W4236525260 title "Rhodium-Catalyzed Reaction of Alkynyl Oxiranes with Arylboronic Acids" @default.
- W4236525260 doi "https://doi.org/10.1055/s-2007-991352" @default.
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