Matches in SemOpenAlex for { <https://semopenalex.org/work/W4236694601> ?p ?o ?g. }
- W4236694601 endingPage "12883" @default.
- W4236694601 startingPage "12878" @default.
- W4236694601 abstract "Abstract Regioselective photodimerization of trans ‐4‐styrylpyridine (4‐spy) derivatives is performed using pseudorotaxane‐like Zn‐based metal organic frameworks MOFs as templates. The formation of rctt ‐HT (head‐to‐tail) dimers is achieved by confining pairs of coordinated 4‐spy derivative ligands within hexagonal windows and then irradiating them with UV light. It is also possible to achieve a photodimerization reaction where two different substituted 4‐spy ligands are included in such a MOF material. The ether bond formation is employed to protect the sensitive ‐OH group of HO‐spy and the methyl group of CH 3 O‐spy is subsequently removed after the formation of cyclobutane derivative in the CH 3 O‐spy‐based MOF. Introducing substituents at the 2‐ or 3‐position of the phenyl group of 4‐spy does not significantly affect the rate of the dimerization process except in the case of the strongly electron‐withdrawing nitro group where the rate is significantly decreased. These results are in striking contrast to the mixtures of photoproducts and low yields obtained by untemplated photodimerization in organic solvents." @default.
- W4236694601 created "2022-05-12" @default.
- W4236694601 creator A5020555164 @default.
- W4236694601 creator A5020744039 @default.
- W4236694601 creator A5036502915 @default.
- W4236694601 creator A5051826494 @default.
- W4236694601 creator A5063605867 @default.
- W4236694601 creator A5082548967 @default.
- W4236694601 date "2018-08-29" @default.
- W4236694601 modified "2023-10-14" @default.
- W4236694601 title "Stereoselective Solid-State Synthesis of Substituted Cyclobutanes Assisted by Pseudorotaxane-like MOFs" @default.
- W4236694601 cites W1955525571 @default.
- W4236694601 cites W1967853599 @default.
- W4236694601 cites W1972593585 @default.
- W4236694601 cites W1978239213 @default.
- W4236694601 cites W1988607914 @default.
- W4236694601 cites W1997817290 @default.
- W4236694601 cites W2004119842 @default.
- W4236694601 cites W2006082515 @default.
- W4236694601 cites W2008164023 @default.
- W4236694601 cites W2011037090 @default.
- W4236694601 cites W2015108171 @default.
- W4236694601 cites W2028990075 @default.
- W4236694601 cites W2038041026 @default.
- W4236694601 cites W2055068613 @default.
- W4236694601 cites W2057573859 @default.
- W4236694601 cites W2062781687 @default.
- W4236694601 cites W2084371616 @default.
- W4236694601 cites W2093559586 @default.
- W4236694601 cites W2109869487 @default.
- W4236694601 cites W2110420387 @default.
- W4236694601 cites W2131020718 @default.
- W4236694601 cites W2144901490 @default.
- W4236694601 cites W2158005694 @default.
- W4236694601 cites W2191645486 @default.
- W4236694601 cites W2213769567 @default.
- W4236694601 cites W2256387064 @default.
- W4236694601 cites W2290886651 @default.
- W4236694601 cites W2320132760 @default.
- W4236694601 cites W2320858939 @default.
- W4236694601 cites W2323707857 @default.
- W4236694601 cites W2324937096 @default.
- W4236694601 cites W2333465965 @default.
- W4236694601 cites W2334389713 @default.
- W4236694601 cites W2410784736 @default.
- W4236694601 cites W2466684561 @default.
- W4236694601 cites W2487516663 @default.
- W4236694601 cites W2571181715 @default.
- W4236694601 cites W2625403022 @default.
- W4236694601 cites W2762570265 @default.
- W4236694601 cites W2766336180 @default.
- W4236694601 cites W2780156136 @default.
- W4236694601 cites W4233036513 @default.
- W4236694601 cites W4238508312 @default.
- W4236694601 cites W4239689209 @default.
- W4236694601 cites W4241225366 @default.
- W4236694601 cites W4242588284 @default.
- W4236694601 cites W4254917982 @default.
- W4236694601 doi "https://doi.org/10.1002/ange.201806076" @default.
- W4236694601 hasPublicationYear "2018" @default.
- W4236694601 type Work @default.
- W4236694601 citedByCount "17" @default.
- W4236694601 countsByYear W42366946012019 @default.
- W4236694601 countsByYear W42366946012020 @default.
- W4236694601 countsByYear W42366946012021 @default.
- W4236694601 countsByYear W42366946012022 @default.
- W4236694601 countsByYear W42366946012023 @default.
- W4236694601 crossrefType "journal-article" @default.
- W4236694601 hasAuthorship W4236694601A5020555164 @default.
- W4236694601 hasAuthorship W4236694601A5020744039 @default.
- W4236694601 hasAuthorship W4236694601A5036502915 @default.
- W4236694601 hasAuthorship W4236694601A5051826494 @default.
- W4236694601 hasAuthorship W4236694601A5063605867 @default.
- W4236694601 hasAuthorship W4236694601A5082548967 @default.
- W4236694601 hasBestOaLocation W42366946012 @default.
- W4236694601 hasConcept C106159729 @default.
- W4236694601 hasConcept C107814960 @default.
- W4236694601 hasConcept C111771559 @default.
- W4236694601 hasConcept C147789679 @default.
- W4236694601 hasConcept C155647269 @default.
- W4236694601 hasConcept C161790260 @default.
- W4236694601 hasConcept C162324750 @default.
- W4236694601 hasConcept C178790620 @default.
- W4236694601 hasConcept C181647583 @default.
- W4236694601 hasConcept C185592680 @default.
- W4236694601 hasConcept C2780377690 @default.
- W4236694601 hasConcept C2780378348 @default.
- W4236694601 hasConcept C2780407432 @default.
- W4236694601 hasConcept C2911029807 @default.
- W4236694601 hasConcept C59759590 @default.
- W4236694601 hasConcept C71240020 @default.
- W4236694601 hasConcept C75473681 @default.
- W4236694601 hasConceptScore W4236694601C106159729 @default.
- W4236694601 hasConceptScore W4236694601C107814960 @default.
- W4236694601 hasConceptScore W4236694601C111771559 @default.
- W4236694601 hasConceptScore W4236694601C147789679 @default.
- W4236694601 hasConceptScore W4236694601C155647269 @default.
- W4236694601 hasConceptScore W4236694601C161790260 @default.