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- W4236756469 abstract "[371-76-7] C2F6Hg (MW 338.60) InChI = 1S/2CF3.Hg/c2*2-1(3)4; InChIKey = JBIKOPZNNQPZLH-UHFFFAOYSA-N (reagent used as a source of difluorocarbene in an array of reactions, also employed occasionally in trifluoromethylation reactions and synthesis of trifluoroalkylmetals) Physical Data: mp 166 °C; d 4.22 g cm−3. Solubility: sol H2O, benzene, and most organic solvents. Form Supplied in: bis(trifluoromethyl)mercury is best prepared by pyrolysis of mercury trifluoroacetate in the presence of anhydrous K2CO3,1 forms colorless crystals that readily sublime. Purification: sublimation (85–95 °C, 760 mm), solution in dry benzene is filtered or chromatographed on silica and benzene is evaporated. Handling, Storage, and Precautions: very poisonous, irritant, should be used only by experienced researchers in a well-ventilated hood. Store refrigerated in a sealed container (slowly sublimes, even at 4 °C, forming large cubic crystals). Stable to moisture and air." @default.
- W4236756469 created "2022-05-12" @default.
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- W4236756469 date "2007-03-15" @default.
- W4236756469 modified "2023-09-27" @default.
- W4236756469 title "Bis(Trifluoromethyl)Mercury" @default.
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- W4236756469 doi "https://doi.org/10.1002/047084289x.rn00709" @default.
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