Matches in SemOpenAlex for { <https://semopenalex.org/work/W4236794920> ?p ?o ?g. }
- W4236794920 endingPage "23293" @default.
- W4236794920 startingPage "23289" @default.
- W4236794920 abstract "Abstract We have established a highly convergent 10‐step route for the total synthesis of (−)‐deoxoapodine, which is a hexacyclic aspidosperma alkaloid. The quaternary C5 center of the characteristic tetrahydrofuran ring was constructed by a chiral‐phosphoric‐acid‐catalyzed enantioselective bromocycloetherification in a 5‐ endo fashion and subsequent allylation by using the Keck protocol. Construction of the aspidosperma skeleton features the formation of a nine‐membered lactam by a catalytic C−H palladation/alkylation cascade at the indole 2‐position and an iron‐catalyzed oxidative transannular reaction at a late‐stage of the synthesis." @default.
- W4236794920 created "2022-05-12" @default.
- W4236794920 creator A5020496617 @default.
- W4236794920 creator A5034267510 @default.
- W4236794920 creator A5040129621 @default.
- W4236794920 creator A5045124669 @default.
- W4236794920 date "2020-10-15" @default.
- W4236794920 modified "2023-10-16" @default.
- W4236794920 title "A Concise Enantioselective Total Synthesis of (−)‐Deoxoapodine" @default.
- W4236794920 cites W1524819480 @default.
- W4236794920 cites W1979979162 @default.
- W4236794920 cites W1984285251 @default.
- W4236794920 cites W1987596278 @default.
- W4236794920 cites W1994983050 @default.
- W4236794920 cites W1999263820 @default.
- W4236794920 cites W2002291219 @default.
- W4236794920 cites W2008251387 @default.
- W4236794920 cites W2012372352 @default.
- W4236794920 cites W2019406135 @default.
- W4236794920 cites W2024323012 @default.
- W4236794920 cites W2031970345 @default.
- W4236794920 cites W2034357559 @default.
- W4236794920 cites W2037928813 @default.
- W4236794920 cites W2046875198 @default.
- W4236794920 cites W2050090042 @default.
- W4236794920 cites W2050408187 @default.
- W4236794920 cites W2050838572 @default.
- W4236794920 cites W2051778898 @default.
- W4236794920 cites W2053460511 @default.
- W4236794920 cites W2064855896 @default.
- W4236794920 cites W2068082622 @default.
- W4236794920 cites W2069308701 @default.
- W4236794920 cites W2075231146 @default.
- W4236794920 cites W2076655264 @default.
- W4236794920 cites W2087003279 @default.
- W4236794920 cites W2087046315 @default.
- W4236794920 cites W2089387611 @default.
- W4236794920 cites W2108821606 @default.
- W4236794920 cites W2114745719 @default.
- W4236794920 cites W2126878522 @default.
- W4236794920 cites W2133524679 @default.
- W4236794920 cites W2158585086 @default.
- W4236794920 cites W2278400746 @default.
- W4236794920 cites W2317574132 @default.
- W4236794920 cites W2318130556 @default.
- W4236794920 cites W2321702693 @default.
- W4236794920 cites W2323636633 @default.
- W4236794920 cites W2334572606 @default.
- W4236794920 cites W2335761431 @default.
- W4236794920 cites W2483119056 @default.
- W4236794920 cites W2522050455 @default.
- W4236794920 cites W2584024975 @default.
- W4236794920 cites W2600671837 @default.
- W4236794920 cites W2616380698 @default.
- W4236794920 cites W2750583009 @default.
- W4236794920 cites W2766917375 @default.
- W4236794920 cites W2786609613 @default.
- W4236794920 cites W2808363512 @default.
- W4236794920 cites W2892082086 @default.
- W4236794920 cites W2903798735 @default.
- W4236794920 cites W2912075118 @default.
- W4236794920 cites W2938718560 @default.
- W4236794920 cites W2950090981 @default.
- W4236794920 cites W2952620472 @default.
- W4236794920 cites W2994938109 @default.
- W4236794920 cites W3004740283 @default.
- W4236794920 cites W3042372773 @default.
- W4236794920 cites W3108855239 @default.
- W4236794920 cites W4230211987 @default.
- W4236794920 cites W4236906650 @default.
- W4236794920 cites W4242249952 @default.
- W4236794920 cites W4250680418 @default.
- W4236794920 cites W4252521057 @default.
- W4236794920 cites W4255210206 @default.
- W4236794920 cites W4255995272 @default.
- W4236794920 cites W4256091906 @default.
- W4236794920 cites W640960312 @default.
- W4236794920 cites W3021943237 @default.
- W4236794920 doi "https://doi.org/10.1002/ange.202010759" @default.
- W4236794920 hasPublicationYear "2020" @default.
- W4236794920 type Work @default.
- W4236794920 citedByCount "7" @default.
- W4236794920 countsByYear W42367949202021 @default.
- W4236794920 countsByYear W42367949202022 @default.
- W4236794920 crossrefType "journal-article" @default.
- W4236794920 hasAuthorship W4236794920A5020496617 @default.
- W4236794920 hasAuthorship W4236794920A5034267510 @default.
- W4236794920 hasAuthorship W4236794920A5040129621 @default.
- W4236794920 hasAuthorship W4236794920A5045124669 @default.
- W4236794920 hasBestOaLocation W42367949201 @default.
- W4236794920 hasConcept C146686406 @default.
- W4236794920 hasConcept C161790260 @default.
- W4236794920 hasConcept C164361826 @default.
- W4236794920 hasConcept C178790620 @default.
- W4236794920 hasConcept C185592680 @default.
- W4236794920 hasConcept C192527728 @default.
- W4236794920 hasConcept C2776055020 @default.
- W4236794920 hasConcept C2776622989 @default.