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- W4236889225 endingPage "2895" @default.
- W4236889225 startingPage "2890" @default.
- W4236889225 abstract "Abstract A method for electrophilic sulfenylation by organophosphorus‐catalyzed deoxygenative O‐atom transfer from sulfonyl chlorides is reported. This C−S bond‐forming reaction is catalyzed by a readily available small‐ring phosphine (phosphetane) in conjunction with a hydrosilane terminal reductant to afford a general entry to sulfenyl electrophiles, including valuable trifluoromethyl, perfluoroalkyl, and heteroaryl derivatives that are otherwise difficult to access. Mechanistic investigations indicate that the twofold deoxygenation of the sulfonyl substrate proceeds by the intervention of an off‐cycle resting state thiophosphonium ion. The catalytic method represents an operationally simple protocol using a stable phosphine oxide as a precatalyst and exhibits broad functional‐group tolerance." @default.
- W4236889225 created "2022-05-12" @default.
- W4236889225 creator A5008032721 @default.
- W4236889225 creator A5024430156 @default.
- W4236889225 creator A5042605335 @default.
- W4236889225 creator A5067372323 @default.
- W4236889225 date "2019-01-25" @default.
- W4236889225 modified "2023-10-14" @default.
- W4236889225 title "Organophosphorus‐Catalyzed Deoxygenation of Sulfonyl Chlorides: Electrophilic (Fluoroalkyl)sulfenylation by P<sup>III</sup>/P<sup>V</sup>=O Redox Cycling" @default.
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- W4236889225 doi "https://doi.org/10.1002/ange.201813919" @default.
- W4236889225 hasPublicationYear "2019" @default.
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