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- W4236975976 abstract "A practical and generally applicable synthesis of the important flavor ingredients corylone (5) and its alkyl homologues 11, 13, 15, and 16 is described, based on alkylation of methyl 4-methoxyacetoacetate (6) with an α-chloro-ketone and subsequent cyclization, hydrolysis, and decarboxylation. The one-pot transformation of methyl 4-chloroacetoacetate to 17 through four consecutive steps is demonstrated. The principle has also been used to prepare the six-membered ring analogues 23 and 24." @default.
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- W4236975976 date "1992-10-30" @default.
- W4236975976 modified "2023-10-14" @default.
- W4236975976 title "Synthesis of Cyclic α-Diones, a Class of Natural Flavor Compounds" @default.
- W4236975976 doi "https://doi.org/10.2533/chimia.1992.399" @default.
- W4236975976 hasPublicationYear "1992" @default.
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