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- W4237121373 abstract "Abstract The dehydrogenation of organosilanes (R x SiH 4− x ) under the formation of Si−Si bonds is an intensively investigated process leading to oligo‐ or polysilanes. The reverse reaction is little studied. To date, the hydrogenolysis of Si−Si bonds requires very harsh conditions and is very unselective, leading to multiple side products. Herein, we describe a new catalytic hydrogenation of oligo‐ and polysilanes that is highly selective and proceeds under mild conditions. New low‐valent nickel hydride complexes are used as catalysts and secondary silanes, RR′SiH 2 , are obtained as products in high purity." @default.
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- W4237121373 date "2020-04-14" @default.
- W4237121373 modified "2023-09-26" @default.
- W4237121373 title "Hydrogenolysis of Polysilanes Catalyzed by Low‐Valent Nickel Complexes" @default.
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- W4237121373 doi "https://doi.org/10.1002/ange.201907525" @default.
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