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- W4237395841 abstract "The cover picture shows a new meso-helical compound, [Zn(dpb)(bdc)(H2O)]n (dpb=1, 4-bis(pyridin-3-ylmethoxy)benzene, H2bdc=1, 4-benzenedicarboxylate). The structure of [Zn(dpb)(bdc)(H2O)]n was refined by single crystal X-ray diffraction with the monoclinic space group C2/c, [Z = 4, a = 18.326(3) Å, b = 5.9882(9) Å, c =21.995(3) Å, and β = 101.910(2)°]. Crystal structure analysis shows that the ZnII ion is five-coordinated in a distorted square-pyramidal geometry, and three dpb ligands are linked by four adjacent zinc ions to form a “Z” shape with a ZnII…ZnII…ZnII…ZnII torsion angle of 93°. Such “Z” shapes are bridged by dpb to form an extraordinary meso-helical chain with Zn…Zn distances of 23.06 Å (Fig. 1). More details are discussed in the article by Xia Li et al. on pp. 785ff." @default.
- W4237395841 created "2022-05-12" @default.
- W4237395841 date "2012-04-01" @default.
- W4237395841 modified "2023-10-16" @default.
- W4237395841 doi "https://doi.org/10.1002/zaac.v638.5" @default.
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