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- W4237398284 abstract "Front Cover: It is demonstrated that liquid-crystalline polypeptides bearing biphenyl mesogens and alkyl tails (i.e., PPLGn-graft-BPCm) can be synthesized by a copper-mediated 1,3-dipolar cycloaddition with quantitative conjugation efficiency. PPLG10-graft-BPC6 with a short main-chain length (n = 10) undergoes an irreversible α-helical to β-sheet transition at ca. 180 °C in the solid-state, whereas the polypeptide samples with a longer main-chain length (n ≥ 54) adopts exclusively an α-helical conformation. A facile synthetic route for the preparation of liquid-crystalline polymers with highly ordered structures is demonstrated. Further details can be found in the article by Q. Yuan, D. Liu, Y. Deng, Y. Ling, H. Tang* on page 196." @default.
- W4237398284 created "2022-05-12" @default.
- W4237398284 date "2015-01-01" @default.
- W4237398284 modified "2023-09-27" @default.
- W4237398284 doi "https://doi.org/10.1002/macp.v216.2" @default.
- W4237398284 hasPublicationYear "2015" @default.
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