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- W4237416084 abstract "The unprecedented dehydration of a selenenic acid (RCH2SeOH) to a selenoaldehyde (RCHSe) has been demonstrated. A primary-alkyl-substituted selenenic acid was synthesized for the first time by taking advantage of a bulky cavity-shaped substituent. Upon heating in solution, the selenenic acid underwent thermal dehydration to produce a stable selenoaldehyde, which was isolated as stable crystals and crystallographically characterized. Investigation of the reaction mechanism revealed that this β dehydration reaction involves two processes, both of which reflect the characteristics of a selenenic acid: 1) dehydrative condensation of two molecules of selenenic acid to generate a selenoseleninate intermediate [RCH2SeSe(O)CH2R], an isomer of a selenenic anhydride, and 2) subsequent β elimination of the selenenic acid from this intermediate to form a CSe double bond, which establishes the self-catalyzed β dehydration of the selenenic acid." @default.
- W4237416084 created "2022-05-12" @default.
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- W4237416084 date "2014-11-19" @default.
- W4237416084 modified "2023-10-14" @default.
- W4237416084 title "Synthesis of a Stable Selenoaldehyde by Self-Catalyzed Thermal Dehydration of a Primary-Alkyl-Substituted Selenenic Acid" @default.
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- W4237416084 doi "https://doi.org/10.1002/ange.201409485" @default.
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