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- W4237732132 abstract "Velocities of exchange of iodine between monolayers at the air/water interface of α-iodostearic acid and potassium iodide in the substrate have been measured over a range of monolayer and substrate concentrations and temperatures using a radioactive tracer technique. The pressure–area isotherms were also determined. The process was followed by measuring the decrease in counting rate immediately above the surface. It is shown theoretically that ions released to the substrate diffuse rapidly and do not contribute appreciably to the counting rate. The velocity of exchange was found to be first order in concentration of the surface phase and of higher but indeterminate order in concentration of potassium iodide. In the region of 18 °C., where a transition from liquid-condensed to liquid-expanded film occurs, the reaction velocity constant undergoes a discontinuous increase. Activation energies of 8.0 and 10.8 kcal./mole were found for exchange in the condensed and expanded films respectively." @default.
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- W4237732132 date "1956-06-01" @default.
- W4237732132 modified "2023-10-05" @default.
- W4237732132 title "RADIOIODINE EXCHANGE BETWEEN IODOSTEARIC ACID MONOLAYERS AND SUBSTRATE IODIDE" @default.
- W4237732132 doi "https://doi.org/10.1139/v56-095" @default.
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