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- W4237751012 abstract "Geometrical isomers of 2-chloro-1-p-nitrophenyl-1-phenylethylene undergo chloride exchange with labelled lithium [36Cl]chloride in dimethylformamide, retaining their configuration. Reaction rates of these compounds, as well as of 2-chloro-1,1-di-(p-nitrophenyl)ethylene and of the corresponding bromo-ethylenes were measured as a function of temperature, within the range 50–140°. Lithium chloride proved a much weaker nucleophile than sodium toluene-p-thiolate, by a factor of 109–1010(at 24°) in the case of the 2-halogeno-1-p-nitrophenyl-1-phenylethylenes." @default.
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- W4237751012 date "1970-01-01" @default.
- W4237751012 modified "2023-09-26" @default.
- W4237751012 title "Stereochemistry and kinetics of nucleophilic substitution of activated 1,1-diaryl-2-halogenoethylenes. Part II" @default.
- W4237751012 doi "https://doi.org/10.1039/j29700000730" @default.
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