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- W4237782893 abstract "Chemo- and site-specific modifications in oligonucleotides have wide applicability as mechanistic probes in chemical biology. Here we have employed a classical reaction in organic chemistry, reductive amination, to selectively functionalize the N<sup>2</sup>-amine of guanine/2’-deoxyguanine monophosphate. This method specifically modifies guanine in several tested DNA oligonucleotides, while leaving the other bases unaffected. Using this approach, we have successfully incorporated desired handles chemoselectively into DNA oligomers." @default.
- W4237782893 created "2022-05-12" @default.
- W4237782893 creator A5006553026 @default.
- W4237782893 creator A5037702644 @default.
- W4237782893 date "2020-06-22" @default.
- W4237782893 modified "2023-10-03" @default.
- W4237782893 title "Selective Functionalization at N2-Position of Guanine in Oligonucleotides via Reductive Amination" @default.
- W4237782893 doi "https://doi.org/10.26434/chemrxiv.12511661" @default.
- W4237782893 hasPublicationYear "2020" @default.
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