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• W4237809595 abstract "A solid-phase approach is described that provides facile access to monofunctionally trans-PtII-modified PNA oligomers of arbitrary sequence for potential use both in antigene and antisense strategies. The approach includes the synthesis of a platinated building block 1 and its subsequent incorporation into three different PNA oligomers 5-7 by solid-phase synthesis. In a model cross-linking reaction one of the latter is found to recognize sequence-specifically a target oligonucleotide 8 and to cross-link to it. The resulting structure is the trans-PtII-cross-linked PNA/DNA duplex 9 as revealed by mass spectrometry in combination with a Maxam-Gilbert sequencing experiment." @default.
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• W4237809595 date "2002-12-16" @default.
• W4237809595 modified "2023-10-17" @default.
• W4237809595 title "Monofunctionallytrans-Diammine Platinum(II)-Modified Peptide Nucleic Acid Oligomers: A New Generation of Potential Antisense Drugs" @default.
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• W4237809595 doi "https://doi.org/10.1002/1521-3765(20021216)8:24<5566::aid-chem5566>3.0.co;2-" @default.
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