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- W4237895477 abstract "Addition of dichlorocarbene to the glycal (±±)-2 followed by cyclopropyl-allyl rearrangement leads to the chloro-2H-pyran (±±)-4. Oxidation of (±±)-4 and reduction of the obtained hydroxypyranone (±±)-5 gave the methyl pyranoside (±±)-6. The relative configuration of (±±)-6 was established by X-ray structural analysis of the corresponding acetate (±±)-7. The synthesis of the optically active starting materials (+)-2 and (−)-2 is also reported." @default.
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- W4237895477 date "2000-05-01" @default.
- W4237895477 modified "2023-09-26" @default.
- W4237895477 doi "https://doi.org/10.1002/(sici)1099-0690(200005)2000:9<1741::aid-ejoc1741>3.3.co;2-n" @default.
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