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- W4237931903 abstract "The synthesis of bis(formazanate) zinc complexes is described. These complexes have well-behaved redox-chemistry, with the ligands functioning as a reversible electron reservoir. This allows the synthesis of bis(formazanate) zinc compounds in three redox states in which the formazanate ligands are reduced to “metallaverdazyl” radicals. The stability of these ligand-based radicals is a result of the delocalization of the unpaired electron over four nitrogen atoms in the ligand backbone. The neutral, anionic, and dianionic compounds (L2Zn0/−1/−2) were fully characterized by single-crystal X-ray crystallography, spectroscopic methods, and DFT calculations. In these complexes, the structural features of the formazanate ligands are very similar to well-known β-diketiminates, but the nitrogen-rich (NNCNN) backbone of formazanates opens the door to redox-chemistry that is otherwise not easily accessible." @default.
- W4237931903 created "2022-05-12" @default.
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- W4237931903 date "2014-02-24" @default.
- W4237931903 modified "2023-10-18" @default.
- W4237931903 title "The Formazanate Ligand as an Electron Reservoir: Bis(Formazanate) Zinc Complexes Isolated in Three Redox States" @default.
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- W4237931903 doi "https://doi.org/10.1002/ange.201309948" @default.
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