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- W4238027174 abstract "The synthesis of unprecedented BINOL-derived cationic phosphonites is described. Through the use of these phosphanes as ancillary ligands in AuI catalysis, a highly regio- and enantioselective assembly of appropriately designed alkynes into 1-(aryl)benzo[5]carbohelicenes is achieved. The modular synthesis of these ligands and the enhanced reactivity that they impart to AuI-centers after coordination have been found to be the key features that allow an optimization of the reaction conditions until the desired benzo[5]helicenes are obtained with high yield and enantioselectivity." @default.
- W4238027174 created "2022-05-12" @default.
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- W4238027174 date "2020-10-21" @default.
- W4238027174 modified "2023-10-12" @default.
- W4238027174 title "Enantioselective Synthesis of 1‐Aryl Benzo[5]helicenes Using BINOL‐Derived Cationic Phosphonites as Ancillary Ligands" @default.
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- W4238027174 doi "https://doi.org/10.1002/ange.202010021" @default.
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