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- W4238035051 abstract "The azide group is a linear bitopic ligand with an effective length of about 2.3 Å, which can function as the X-site with an end-to-end coordination mode to accommodate a wide range of organic amine cations. This chapter summarizes the synthesis, structural diversity, phase transitions, and physical properties of hybrid azide perovskites. Changing the divalent metals for a combination of mono- and trivalent ones gives rise to a subclass of azides possessing hybrid double-perovskite structures. Compared with conventional perovskite oxides, azide hybrid organic–inorganic perovskites exhibit two significant differences: lower formula weights and more flexible framework structures. These two unique features could lead to significant energetic changes across phase transitions induced via the vibration of crystal lattice. The versatile A-site organic amine cations and B-site metals give rise to abundant physical properties, which include magnetic, dielectric, ferroic, and mechanical properties and the combination of them." @default.
- W4238035051 created "2022-05-12" @default.
- W4238035051 date "2020-06-26" @default.
- W4238035051 modified "2023-10-18" @default.
- W4238035051 title "Hybrid Azide Perovskites" @default.
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- W4238035051 doi "https://doi.org/10.1002/9783527344338.ch4" @default.
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