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- W4238049529 endingPage "15921" @default.
- W4238049529 startingPage "15917" @default.
- W4238049529 abstract "Abstract Metal‐free activation of homoatomic E−E σ bonds (E=P, B) in white phosphorus (P 4 ) and bis(catecholato)diboron (B 2 cat 2 ) with a 1,2‐diboraallene 1 is reported. The 1:1 and 1:2 reactions of P 4 with 1 afford B n P 4 cages ( 2 : n =2, 3 : n =4), whereas a stoichiometric mixture of 1 and B 2 cat 2 undergoes homonuclear catenation through the addition of the B−B σ bond of B 2 cat 2 across the B=B double bond of 1 (i.e. diboration), which leads to the formation of a tetraborane ( 4 ) featuring a B 4 chain." @default.
- W4238049529 created "2022-05-12" @default.
- W4238049529 creator A5044080227 @default.
- W4238049529 creator A5047082473 @default.
- W4238049529 creator A5048588199 @default.
- W4238049529 creator A5054562744 @default.
- W4238049529 creator A5086976206 @default.
- W4238049529 date "2018-11-08" @default.
- W4238049529 modified "2023-10-09" @default.
- W4238049529 title "Facile Activation of Homoatomic σ Bonds in White Phosphorus and Diborane by a Diboraallene" @default.
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