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- W4238088328 abstract "The trisaccharide segment of the phenolic glycolipid (PGL) of Mycobacterium tuberculosis, 2-O-methyl-3-O-[3-O-(2, 3, 4-tri-O-methyl-α-L-fucopyranosyl)-α-L-rhamnopyranosyl]-α-L-rhamnopyranose, was synthesized in the form of the p-(2-methoxycarbonylethyl)phenyI glycoside by a stepwise condensation. 2, 4-Di-O-benzyl-3-O-acetyl-α-L-rhamnopyranosyl chloride was coupled to p-(2-methoxycarbonylethyl)phenyl 4-O-benzyl-2-O-methyl-α-L-rhamnopyranoside in the presence of silver triflate, and 2, 3, 4-tri-O-methyl-α-L-rhamnopyranosyl chloride was then coupled to the deacetylated disaccharide by the same procedure. The trisaccharide was deblocked and coupled to BSA, giving the neoglycoconjugate TB-NT-P-BSA. TB-NT-P-BSA showed its possibility as a useful tool for the serodiagnosis of tuberculosis." @default.
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- W4238088328 date "1991-01-01" @default.
- W4238088328 modified "2023-10-17" @default.
- W4238088328 title "Synthesis of the Trisaccharide-Protein Conjugate of the Phenolic Glycolipid of Mycobacterium tuberculosis for the Serodiagnosis of Tuberculosis." @default.
- W4238088328 doi "https://doi.org/10.1271/bbb1961.55.2123" @default.
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