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- W4238088779 abstract "Publisher SummaryThe chapter discusses the synthesis of reaction systems. The reaction system is the core of a chemical process. It is also the starting point in process design. By proper selection and design of the chemical reaction system, the modern process plants must cope with large flexibility with respect to production rate and selectivity. A greater attention should be paid to the formation of by-products and impurities. The selection and the design of the reactor system must be done in the context of interactions with the whole process, particularly with the separation system. The chemical transformation among the components involved in a network of chemical reactions can be described quantitatively by means of stoichiometric relations. Chemical equilibrium is another key issue in process design. Chemical equilibrium might set in many cases an upper limit for the achievable conversion, if nothing is done to remove one of the products from the reaction space. Because the equilibrium conversion is independent of kinetics and reactor design, it is also convenient to use it as reference. Important industrial reactions take place close to equilibrium—such as the synthesis of ammonia and methanol, esterification of acids with alcohols and dehydrogenations—particularly when the reaction rate is fast. Therefore, the investigation of chemical equilibrium should be done systematically in a design project." @default.
- W4238088779 created "2022-05-12" @default.
- W4238088779 date "2003-01-01" @default.
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- W4238088779 title "Chapter 8 Synthesis of reaction systems" @default.
- W4238088779 doi "https://doi.org/10.1016/s1570-7946(03)80032-9" @default.
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