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- W4238099470 abstract "Abstract The highly efficient electrophilic cyanation of boron enolates using readily available cyanating reagents, N ‐cyano‐ N ‐phenyl‐ p ‐toluenesulfonamide (NCTS) and p ‐toluenesulfonyl cyanide (TsCN), is reported. Various β‐ketonitriles were prepared by this new protocol, which has a remarkably broad substrate scope compared to existing methods. The present method also allowed efficient synthesis of β‐ketonitriles containing a quaternary α‐carbon center. In addition, a preliminary result with the use of a chiral boron enolate for the enantioselective cyanation reaction is described." @default.
- W4238099470 created "2022-05-12" @default.
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- W4238099470 date "2016-07-15" @default.
- W4238099470 modified "2023-10-14" @default.
- W4238099470 title "Electrophilic Cyanation of Boron Enolates: Efficient Access to Various β-Ketonitrile Derivatives" @default.
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- W4238099470 doi "https://doi.org/10.1002/ange.201605445" @default.
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