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- W4238099573 abstract "A theoretical treatment is given of the i−E curves on a rotating disk electrode for a simple redox reaction O+ne η R when both O and R can be adsorbed. It is assumed that a Langmuir isotherm is obeyed and that the adsorption rate is not a limiting factor. The relative importance of the surface (between adsorbed species) and of the heterogeneous (between nonadsorbed species) electrochemical reactions depends on the ratio of the rate constants ks and kh for the two processes, on the product and on the ratio of the adsorption coefficients of O and R, and on the potential. Practical implications of the theory are discussed on the basis of a relationship established by Brown and Anson between ks and kh. It is shown that, with the above assumptions, electrochemical reactions should take place in most cases via the adsorbed species in aqueous medium. Conversely, in non-aqueous media, reactions can be found for which the influence of adsorption is negligible, although cases can exist for which the participation of adsorbed species has to be considered. Consequences are discussed concerning the verification of Marcus' theory (dependence of the transfer coefficient on the potential, magnitude of the heterogeneous rate constant) and the influence of the electrode material on the heterogeneous rate constant." @default.
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- W4238099573 date "1981-07-10" @default.
- W4238099573 modified "2023-09-27" @default.
- W4238099573 title "Theoretical study of a simple redox system with adsorption of the reactants on a rotating disk electrode Part I. The reaction path in the case of a langmuirian adsorption equilibrium" @default.
- W4238099573 doi "https://doi.org/10.1016/0368-1874(81)87103-1" @default.
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