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• W4238178200 abstract "Abstract Oxidative thermal removal of the polymeric templates is not trivial for molybdenum oxides and hampers mesostructuring of this material. At ambient oxygen fugacity, Mo VI is the thermodynamically stable oxidation state and sublimation of MoO 3 leads to a quick loss of the mesostructure through Oswald ripening. Taking advantage of the Boudouard equilibrium allows to fix the oxygen fugacity at a level where non‐volatile MoO 2− x is stable while carbonaceous material may be oxidized by CO 2 . Mesostructured MoO 2− x can be chemically converted into MoO 3 or MoN under retention of the mesostructure." @default.
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• W4238178200 date "2017-01-03" @default.
• W4238178200 modified "2023-10-02" @default.
• W4238178200 title "Template Removal via Boudouard Equilibrium Allows for Synthesis of Mesostructured Molybdenum Compounds" @default.
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• W4238178200 doi "https://doi.org/10.1002/ange.201610786" @default.
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