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- W4238282894 abstract "Abstract The electrochemical performance of the aluminum‐sulfur (Al‐S) battery has very poor reversibility and a low charge/discharge current density owing to slow kinetic processes determined by an inevitable dissociation reaction from Al 2 Cl 7 − to free Al 3+ . Al 2 Cl 6 Br − was used instead of Al 2 Cl 7 − as the dissociation reaction reagent. A 15‐fold faster reaction rate of Al 2 Cl 6 Br − dissociation than that of Al 2 Cl 7 − was confirmed by density function theory calculations and the Arrhenius equation. This accelerated dissociation reaction was experimentally verified by the increase of exchange current density during Al electro‐deposition. Using Al 2 Cl 6 Br − instead of Al 2 Cl 7 − , a kinetically accelerated Al‐S battery has a sulfur utilization of more than 80 %, with at least four times the sulfur content and five times the current density than that of previous work." @default.
- W4238282894 created "2022-05-12" @default.
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- W4238282894 date "2018-01-16" @default.
- W4238282894 modified "2023-10-16" @default.
- W4238282894 title "An Aluminum-Sulfur Battery with a Fast Kinetic Response" @default.
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- W4238282894 doi "https://doi.org/10.1002/ange.201711328" @default.
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