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- W4238289940 abstract "Abstract Herein, we report a user‐friendly and metal‐free UV‐A light mediated borocyclopropanation of styrenes using continuous flow technology. A broad range of styrene derivatives can be cyclopropanated in good yields within 1 h residence time to produce highly valuable cyclopropylboronate esters with modest to good diastereoselectivities. The reaction is also applicable to α‐substituted styrenes. Mechanistic studies support a photoredox process during which xanthone, a well‐known organic photosensitizer, can easily reach a photoexcited state that is available for both an oxidative and a reductive quenching." @default.
- W4238289940 created "2022-05-12" @default.
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- W4238289940 date "2018-09-12" @default.
- W4238289940 modified "2023-10-15" @default.
- W4238289940 title "Borocyclopropanation of Styrenes Mediated by UV-light Under Continuous Flow Conditions" @default.
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- W4238289940 doi "https://doi.org/10.1002/ange.201807347" @default.
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