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- W4238333592 abstract "Numerous unsaturated substrate molecules undergo migratory insertion with metal-carbon bonds. Recent attention has been focused on insertion of CO and alkenes into d8 metal hydrocarbyl and acyl bonds with the aim of understanding the fundamental steps involved. Knowledge of ligand control over rates and regioselectivity of the insertion reaction would allow the design of highly active and selective catalyst systems for a whole range of carbon-carbon bond forming reactions. Herein are summarised recent advances in delineating the detailed aspects of the insertion mechanism and ligand influences on rates and regioselectivity. Investigations have provided information on the nature of pre- and post-insertion intermediates; the nature of the carbon-carbon bond forming step; ligand control, and advances in theoretical modelling of the details of the intricate insertion reaction." @default.
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- W4238333592 date "1996-11-01" @default.
- W4238333592 modified "2023-09-26" @default.
- W4238333592 title "Recent fundamental studies on migratory insertion into metal-carbon bonds" @default.
- W4238333592 doi "https://doi.org/10.1016/s0010-8545(96)01280-5" @default.
- W4238333592 hasPublicationYear "1996" @default.
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