Matches in SemOpenAlex for { <https://semopenalex.org/work/W4238333608> ?p ?o ?g. }
- W4238333608 endingPage "3981" @default.
- W4238333608 startingPage "3973" @default.
- W4238333608 abstract "Fifteen substituted maleimide cycloadducts of anthracene derivatives were synthesized in one or two steps from available precursors in yields ranging from 32 to 63%. They differ in the nature of the group on the maleimide nitrogen atom and of the substituents on the anthracene platform. In all instances, the introduction of a maleimide bridge across positions 9 and 10 of the anthracene skeleton isolates electronically its peripheral phenylene rings and suppresses its characteristic fluorescence. The cycloadducts with a 4-(dimethylamino)phenyl group on the maleimide nitrogen atom undergo retro-cycloaddition upon ultraviolet illumination with quantum yields ranging from 0.001 to 0.01. This structural transformation restores the aromatic character of the central ring of the oligoacene chromophore and activates its emission with fluorescence quantum yields ranging from 0.07 to 0.85. Thus, this particular choice of building blocks for the construction of photoresponsive compounds can translate into viable operating principles for fluorescence activation and, ultimately, lead to the realization of valuable photoactivatable fluorophores for imaging applications." @default.
- W4238333608 created "2022-05-12" @default.
- W4238333608 creator A5021052744 @default.
- W4238333608 creator A5058820456 @default.
- W4238333608 creator A5078476719 @default.
- W4238333608 date "2014-04-21" @default.
- W4238333608 modified "2023-10-18" @default.
- W4238333608 title "Photoactivatable Anthracenes" @default.
- W4238333608 cites W1486997076 @default.
- W4238333608 cites W1836464350 @default.
- W4238333608 cites W1963660636 @default.
- W4238333608 cites W1966203933 @default.
- W4238333608 cites W1972533474 @default.
- W4238333608 cites W1976052973 @default.
- W4238333608 cites W1976740938 @default.
- W4238333608 cites W1984369207 @default.
- W4238333608 cites W1985964434 @default.
- W4238333608 cites W1987387392 @default.
- W4238333608 cites W1993569566 @default.
- W4238333608 cites W1996426210 @default.
- W4238333608 cites W1997151511 @default.
- W4238333608 cites W2001239075 @default.
- W4238333608 cites W2001324230 @default.
- W4238333608 cites W2001417990 @default.
- W4238333608 cites W2005719010 @default.
- W4238333608 cites W2014603223 @default.
- W4238333608 cites W2021529941 @default.
- W4238333608 cites W2023271753 @default.
- W4238333608 cites W2025623778 @default.
- W4238333608 cites W2025750064 @default.
- W4238333608 cites W2026364734 @default.
- W4238333608 cites W2027825885 @default.
- W4238333608 cites W2028258211 @default.
- W4238333608 cites W2028581135 @default.
- W4238333608 cites W2030271964 @default.
- W4238333608 cites W2034516685 @default.
- W4238333608 cites W2034537588 @default.
- W4238333608 cites W2043483484 @default.
- W4238333608 cites W2048902550 @default.
- W4238333608 cites W2055186784 @default.
- W4238333608 cites W2057459960 @default.
- W4238333608 cites W2059994507 @default.
- W4238333608 cites W2062738453 @default.
- W4238333608 cites W2066807821 @default.
- W4238333608 cites W2067046952 @default.
- W4238333608 cites W2069061201 @default.
- W4238333608 cites W2069954324 @default.
- W4238333608 cites W2071777689 @default.
- W4238333608 cites W2078408605 @default.
- W4238333608 cites W2080907827 @default.
- W4238333608 cites W2084125438 @default.
- W4238333608 cites W2086957099 @default.
- W4238333608 cites W2087681398 @default.
- W4238333608 cites W2091419082 @default.
- W4238333608 cites W2111307291 @default.
- W4238333608 cites W2125160663 @default.
- W4238333608 cites W2131350133 @default.
- W4238333608 cites W2141981357 @default.
- W4238333608 cites W2157456092 @default.
- W4238333608 cites W2160079170 @default.
- W4238333608 cites W2168816122 @default.
- W4238333608 cites W2168903059 @default.
- W4238333608 cites W2169873791 @default.
- W4238333608 cites W2313907546 @default.
- W4238333608 cites W2318696264 @default.
- W4238333608 cites W2319097948 @default.
- W4238333608 cites W2319336570 @default.
- W4238333608 cites W2323931536 @default.
- W4238333608 cites W2335365135 @default.
- W4238333608 cites W2491458126 @default.
- W4238333608 cites W3004789430 @default.
- W4238333608 doi "https://doi.org/10.1021/jo5004482" @default.
- W4238333608 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/24716594" @default.
- W4238333608 hasPublicationYear "2014" @default.
- W4238333608 type Work @default.
- W4238333608 citedByCount "20" @default.
- W4238333608 countsByYear W42383336082014 @default.
- W4238333608 countsByYear W42383336082015 @default.
- W4238333608 countsByYear W42383336082016 @default.
- W4238333608 countsByYear W42383336082017 @default.
- W4238333608 countsByYear W42383336082018 @default.
- W4238333608 countsByYear W42383336082019 @default.
- W4238333608 countsByYear W42383336082020 @default.
- W4238333608 countsByYear W42383336082021 @default.
- W4238333608 countsByYear W42383336082022 @default.
- W4238333608 crossrefType "journal-article" @default.
- W4238333608 hasAuthorship W4238333608A5021052744 @default.
- W4238333608 hasAuthorship W4238333608A5058820456 @default.
- W4238333608 hasAuthorship W4238333608A5078476719 @default.
- W4238333608 hasConcept C121332964 @default.
- W4238333608 hasConcept C161790260 @default.
- W4238333608 hasConcept C178790620 @default.
- W4238333608 hasConcept C185592680 @default.
- W4238333608 hasConcept C188027245 @default.
- W4238333608 hasConcept C192468462 @default.
- W4238333608 hasConcept C2779563022 @default.
- W4238333608 hasConcept C2779664164 @default.
- W4238333608 hasConcept C2780105360 @default.