Matches in SemOpenAlex for { <https://semopenalex.org/work/W4238451884> ?p ?o ?g. }
Showing items 1 to 60 of
60
with 100 items per page.
- W4238451884 endingPage "276" @default.
- W4238451884 startingPage "267" @default.
- W4238451884 abstract "Abstract Phosphorus(III) reagents are known to undergo reaction with 1,2‐dicarbonyl compounds to give adducts of formal P ‐addition to the carbonyl oxygen (Kukhtin‐Ramirez reaction). We have shown that these Kukhtin‐Ramirez adducts further react to incorporate a range of N ‐, O ‐, and C ‐based protic pronucleophiles with expulsion of a phosphine oxide by‐product. The process likely proceeds in stepwise fashion, initiated by proton transfer from the protic pronucleophile to the Kukhtin‐Ramirez adduct, followed by Arbuzov‐like displacement of the phosphine oxide leaving group. This reaction sequence therefore represents a convenient one pot process for access to a range of α–functionalized carbonyl compounds from readily available reagents and precursors." @default.
- W4238451884 created "2022-05-12" @default.
- W4238451884 creator A5024245413 @default.
- W4238451884 creator A5024430156 @default.
- W4238451884 date "2016-03-04" @default.
- W4238451884 modified "2023-10-14" @default.
- W4238451884 title "Phosphorus(III)-Mediated Reductive Condensation of α-Keto Esters and Protic Pronucleophiles" @default.
- W4238451884 cites W1988245632 @default.
- W4238451884 cites W2139795003 @default.
- W4238451884 cites W2146115006 @default.
- W4238451884 cites W2167465587 @default.
- W4238451884 cites W2178638536 @default.
- W4238451884 cites W2950649780 @default.
- W4238451884 cites W2953081539 @default.
- W4238451884 cites W2953278621 @default.
- W4238451884 doi "https://doi.org/10.1002/0471264229.os092.20" @default.
- W4238451884 hasPublicationYear "2016" @default.
- W4238451884 type Work @default.
- W4238451884 citedByCount "0" @default.
- W4238451884 crossrefType "other" @default.
- W4238451884 hasAuthorship W4238451884A5024245413 @default.
- W4238451884 hasAuthorship W4238451884A5024430156 @default.
- W4238451884 hasBestOaLocation W42384518842 @default.
- W4238451884 hasConcept C108204754 @default.
- W4238451884 hasConcept C155647269 @default.
- W4238451884 hasConcept C161790260 @default.
- W4238451884 hasConcept C178790620 @default.
- W4238451884 hasConcept C185592680 @default.
- W4238451884 hasConcept C2777716191 @default.
- W4238451884 hasConcept C2781082197 @default.
- W4238451884 hasConcept C40875361 @default.
- W4238451884 hasConcept C510538283 @default.
- W4238451884 hasConceptScore W4238451884C108204754 @default.
- W4238451884 hasConceptScore W4238451884C155647269 @default.
- W4238451884 hasConceptScore W4238451884C161790260 @default.
- W4238451884 hasConceptScore W4238451884C178790620 @default.
- W4238451884 hasConceptScore W4238451884C185592680 @default.
- W4238451884 hasConceptScore W4238451884C2777716191 @default.
- W4238451884 hasConceptScore W4238451884C2781082197 @default.
- W4238451884 hasConceptScore W4238451884C40875361 @default.
- W4238451884 hasConceptScore W4238451884C510538283 @default.
- W4238451884 hasLocation W42384518841 @default.
- W4238451884 hasLocation W42384518842 @default.
- W4238451884 hasOpenAccess W4238451884 @default.
- W4238451884 hasPrimaryLocation W42384518841 @default.
- W4238451884 hasRelatedWork W179201808 @default.
- W4238451884 hasRelatedWork W2020634109 @default.
- W4238451884 hasRelatedWork W2076997633 @default.
- W4238451884 hasRelatedWork W2386246495 @default.
- W4238451884 hasRelatedWork W243733273 @default.
- W4238451884 hasRelatedWork W2949140480 @default.
- W4238451884 hasRelatedWork W3034187991 @default.
- W4238451884 hasRelatedWork W3102151787 @default.
- W4238451884 hasRelatedWork W3117280119 @default.
- W4238451884 hasRelatedWork W4206038276 @default.
- W4238451884 isParatext "false" @default.
- W4238451884 isRetracted "false" @default.
- W4238451884 workType "other" @default.