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- W4238476942 endingPage "14624" @default.
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- W4238476942 abstract "The Sonogashira coupling of γ-CD-encapsulated alkynylpyrenes with terphenyl-type stopper molecules gave a doubly alkynylpyrene-threaded [4]rotaxane. The rotaxane showed only excimer emission, with a high fluorescence quantum yield of Φf=0.37, arising from the spatially restricted excimer within the cavity of the γ-CD. The excimer emission suffered little from self-quenching up to a concentration of 1.5×10−5 M and was circularly polarized with a high glum value of −1.5×10−2. The strong circularly polarized luminescence may result from the two stacked pyrenes existing in the rotaxane in an asymmetrically twisted manner." @default.
- W4238476942 created "2022-05-12" @default.
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- W4238476942 date "2014-10-27" @default.
- W4238476942 modified "2023-10-03" @default.
- W4238476942 title "A Doubly Alkynylpyrene-Threaded [4]Rotaxane That Exhibits Strong Circularly Polarized Luminescence from the Spatially Restricted Excimer" @default.
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- W4238476942 doi "https://doi.org/10.1002/ange.201408193" @default.
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