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- W4238493403 abstract "The cyclopentadienyl (Cp) group is a very important ligand for many transition-metal complexes which have been applied in catalysis. The availability of chiral cyclopentadienyl ligands (Cpx) lags behind other ligand classes, thus hampering the investigation of enantioselective processes. We report a library of chiral CpxIrIII complexes equipped with an atropchiral Cp scaffold. A robust complexation procedure reliably provides CpxIrIII complexes with tunable counterions. In a proof-of-concept application, the iodide-bearing members are shown to be highly selective for enyne cycloisomerization reactions. The dehydropiperidine-fused cyclopropane products are formed in good yields and enantioselectivities." @default.
- W4238493403 created "2022-05-12" @default.
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- W4238493403 date "2015-08-27" @default.
- W4238493403 modified "2023-10-07" @default.
- W4238493403 title "Chiral Cyclopentadienyl Iridium(III) Complexes Promote Enantioselective Cycloisomerizations Giving Fused Cyclopropanes" @default.
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- W4238493403 doi "https://doi.org/10.1002/ange.201506483" @default.
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