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- W4238596112 abstract "Positiver Wassereffekt: Ein Katalysator aus [Pd2(dba)3] (dba=Dibenzylidenaceton) und (S)-Siphos-PE bewirkt die enantioselektive Kupplung von N-Allylharnstoffen mit Arylbromiden zu 4-substituierten Imidazolidin-2-onen. Zusätze von Wasser führen zu deutlich erhöhten Enantioselektivitäten mit elektronenarmen Arylhalogenidsubstraten. Es wird vermutet, dass die reduktive Eliminierung unter C-C-Bindungsbildung der enantioselektive Schritt dieser Reaktionen ist." @default.
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- W4238596112 date "2012-08-31" @default.
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- W4238596112 title "Synthesis of Enantiomerically Enriched Imidazolidin-2-Ones through Asymmetric Palladium-Catalyzed Alkene Carboamination Reactions" @default.
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- W4238596112 doi "https://doi.org/10.1002/ange.201205233" @default.
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