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- W4238668839 abstract "A series of Ni(II) trinuclear complexes, [Ni<sub>3</sub>(sala-X)<sub>6</sub>] (sala-X = <i>o</i>-[(<i>p</i>-X-phenylimino)methyl]phenol; X = Br <b>1-Br</b>, Me <b>1-Me</b> and OMe <b>1-OMe</b>), have been prepared and fully characterised. X-ray crystallographic studies reveal that the complexes are composed of <a>three face-sharing octahedral Ni(II) metal ions bridged by the phenoxide oxygens of the sala-X ligands</a>. Magnetic studies indicate that the magnetic Ni(II) centres are ferromagnetically coupled with the substituent group having only a minor impact on the magnitude of coupling. DFT calculations also support ferromagnetic coupling with smaller Ni-O-Ni angles leading to slightly larger coupling constants in line with previous studies." @default.
- W4238668839 created "2022-05-12" @default.
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- W4238668839 date "2021-04-28" @default.
- W4238668839 modified "2023-09-25" @default.
- W4238668839 title "Nickel(II) Salicylaldiminates: Re-Visiting a Classic" @default.
- W4238668839 doi "https://doi.org/10.26434/chemrxiv.14493756.v1" @default.
- W4238668839 hasPublicationYear "2021" @default.
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