Matches in SemOpenAlex for { <https://semopenalex.org/work/W4238697539> ?p ?o ?g. }
- W4238697539 endingPage "6" @default.
- W4238697539 startingPage "1" @default.
- W4238697539 abstract "[838-85-7] C12H11O4P (MW 250.19) InChI = 1S/C12H11O4P/c13-17(14,15-11-7-3-1-4-8-11)16-12-9-5-2-6-10-12/h1-10H,(H,13,14) InChIKey = ASMQGLCHMVWBQR-UHFFFAOYSA-N (phosphorylation,43, 53 Brønsted acid catalyst for reactions, including acetalization,8 Friedländer,11 Pictet–Spengler,18 Michael,25 imine reduction,35 and polymerization61) Alternate Names: phosphoric acid diphenyl ester, diphenyl hydrogen phosphate, diphenyl phosphate, DPP. Physical Data: mp 62–70 °C,1 (51 °C dihydrate),2 bp 280 °C, density 0.76 g cm−3, pKa = 3.88 (dry DMSO).3 Solubility: soluble in most organic solvents. Form Supplied in: white crystalline solid. Analysis of Reagent Purity: NMR and MS. Preparative Methods: treat diphenyl phosphorochloridate with 2N NaOH until it dissolves and then acidify with HCl.2, 4 The dihydrate of DPP can be synthesized from P4O10 and phenol.2 Purification: wash with 6M HCl followed by recrystallization with ethanol. Handling, Storage, and Precautions: it can be stored indefinitely at room temperature. It may be harmful if inhaled, absorbed through skin, or swallowed. It may cause skin, eye, or respiratory tract irritation." @default.
- W4238697539 created "2022-05-12" @default.
- W4238697539 creator A5059738190 @default.
- W4238697539 date "2014-10-20" @default.
- W4238697539 modified "2023-09-24" @default.
- W4238697539 title "Diphenylphosphoric Acid" @default.
- W4238697539 cites W1970790686 @default.
- W4238697539 cites W1974195686 @default.
- W4238697539 cites W1977732935 @default.
- W4238697539 cites W1981104362 @default.
- W4238697539 cites W1987571489 @default.
- W4238697539 cites W1995293569 @default.
- W4238697539 cites W2008678360 @default.
- W4238697539 cites W2011543575 @default.
- W4238697539 cites W2018846002 @default.
- W4238697539 cites W2019937274 @default.
- W4238697539 cites W2020296405 @default.
- W4238697539 cites W2025165750 @default.
- W4238697539 cites W2026874072 @default.
- W4238697539 cites W2033204831 @default.
- W4238697539 cites W2036675288 @default.
- W4238697539 cites W2036848720 @default.
- W4238697539 cites W2038082597 @default.
- W4238697539 cites W2051818700 @default.
- W4238697539 cites W2054312445 @default.
- W4238697539 cites W2056286548 @default.
- W4238697539 cites W2056318800 @default.
- W4238697539 cites W2063357708 @default.
- W4238697539 cites W2064530764 @default.
- W4238697539 cites W2065478100 @default.
- W4238697539 cites W2069551754 @default.
- W4238697539 cites W2069725905 @default.
- W4238697539 cites W2074557407 @default.
- W4238697539 cites W2075447800 @default.
- W4238697539 cites W2086618770 @default.
- W4238697539 cites W2091938890 @default.
- W4238697539 cites W2097650533 @default.
- W4238697539 cites W2103006040 @default.
- W4238697539 cites W2104471430 @default.
- W4238697539 cites W2109457927 @default.
- W4238697539 cites W2112874490 @default.
- W4238697539 cites W2127825859 @default.
- W4238697539 cites W2133197779 @default.
- W4238697539 cites W2142852194 @default.
- W4238697539 cites W2146066038 @default.
- W4238697539 cites W2148629973 @default.
- W4238697539 cites W2150865621 @default.
- W4238697539 cites W2152037035 @default.
- W4238697539 cites W2155702692 @default.
- W4238697539 cites W2155963884 @default.
- W4238697539 cites W2163241765 @default.
- W4238697539 cites W2175329910 @default.
- W4238697539 cites W2175673971 @default.
- W4238697539 cites W2313765826 @default.
- W4238697539 cites W2315142592 @default.
- W4238697539 cites W2320650853 @default.
- W4238697539 cites W2321689970 @default.
- W4238697539 cites W2325877598 @default.
- W4238697539 cites W2327690129 @default.
- W4238697539 cites W2331059667 @default.
- W4238697539 cites W2513662746 @default.
- W4238697539 cites W2949413656 @default.
- W4238697539 cites W2949428587 @default.
- W4238697539 cites W2949581547 @default.
- W4238697539 cites W2950163064 @default.
- W4238697539 cites W2950338821 @default.
- W4238697539 cites W2950380360 @default.
- W4238697539 cites W2951199696 @default.
- W4238697539 cites W2951242099 @default.
- W4238697539 cites W2951766458 @default.
- W4238697539 cites W2952577987 @default.
- W4238697539 cites W2952755109 @default.
- W4238697539 cites W2953367248 @default.
- W4238697539 doi "https://doi.org/10.1002/047084289x.rn01742" @default.
- W4238697539 hasPublicationYear "2014" @default.
- W4238697539 type Work @default.
- W4238697539 citedByCount "5" @default.
- W4238697539 countsByYear W42386975392016 @default.
- W4238697539 countsByYear W42386975392020 @default.
- W4238697539 countsByYear W42386975392021 @default.
- W4238697539 countsByYear W42386975392022 @default.
- W4238697539 countsByYear W42386975392023 @default.
- W4238697539 crossrefType "reference-entry" @default.
- W4238697539 hasAuthorship W4238697539A5059738190 @default.
- W4238697539 hasConcept C13965031 @default.
- W4238697539 hasConcept C151730666 @default.
- W4238697539 hasConcept C155574463 @default.
- W4238697539 hasConcept C161790260 @default.
- W4238697539 hasConcept C178790620 @default.
- W4238697539 hasConcept C185592680 @default.
- W4238697539 hasConcept C195702682 @default.
- W4238697539 hasConcept C2776622989 @default.
- W4238697539 hasConcept C2777132085 @default.
- W4238697539 hasConcept C2777702071 @default.
- W4238697539 hasConcept C2780161600 @default.
- W4238697539 hasConcept C40875361 @default.
- W4238697539 hasConcept C86803240 @default.
- W4238697539 hasConceptScore W4238697539C13965031 @default.