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- W4238784823 abstract "In the title complex, [Co(C7H4ClO2)2(C6H6N2O)2(H2O)2], the Co(II) atom is located on an inversion center and is coordinated by two 3-chloro-benzoate (CB) anions, two nicotinamide (NA) ligands and two water mol-ecules. The four O atoms in the equatorial plane form a slightly distorted square-planar arrangement, while the slightly distorted octa-hedral coordination is completed by the two N atoms of the NA ligands in the axial positions. The dihedral angle between the carboxyl-ate group and the adjacent benzene ring is 9.14 (9)°, while the pyridine and benzene rings are oriented at a dihedral angle of 82.18 (8)°. In the crystal, N-H⋯O and O-H⋯O hydrogen bonds link the mol-ecules into a two-dimensional network lying parallel to (101). π-π stacking between parallel pyridine rings of adjacent mol-ecules [centroid-centroid distance = 3.7765 (8) Å] further stabilizes the crystal structure." @default.
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- W4238784823 date "2013-05-31" @default.
- W4238784823 modified "2023-09-23" @default.
- W4238784823 title "Diaquabis(3-chlorobenzoato-κ<i>O</i>)bis(nicotinamide-κ<i>N</i><sup>1</sup>)cobalt(II)" @default.
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- W4238784823 doi "https://doi.org/10.1107/s160053681301458x" @default.
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