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- W4239030090 abstract "The iodine-sodium iodide system in acetonitrile has been investigated potentiometrically without use of inert electrolyte at concentrations ranging from 10−6 to 1.5 m iodine and from 10−5 to 0.5 m iodide. The arrangement of the concentration cell eliminated the need for any other reference electrode; liquid junction potentials were estimated to be below 1 mV. From measurements at uniform ionic strength throughout the cell the association constant at zero ionic strength was evaluated by extrapolation. Standard thermodynamic data were calculated yielding almost zero entropy of association. The extrapolation method and the resulting data are discussed; evaluated association constants at 25 and 50°C are compared with literature data. Also reported are association constants of iodine and iodide in propionitrile, dimethylformamide, and methanol." @default.
- W4239030090 created "2022-05-12" @default.
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- W4239030090 date "1971-09-01" @default.
- W4239030090 modified "2023-10-18" @default.
- W4239030090 title "The iodine—iodine system in acetonitrile Evaluation of standard thermodynamic data on the association I−+I2 = 1−3 from potentiometric measurements at 25 and 50°C" @default.
- W4239030090 doi "https://doi.org/10.1016/0368-1874(71)85109-2" @default.
- W4239030090 hasPublicationYear "1971" @default.
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