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- W4239067438 abstract "Abstract Synthesizing 2D metal–organic frameworks (2D MOFs) in high yields and rational tailoring of the properties in a predictable manner for specific applications is extremely challenging. Now, a series of porphyrin‐based 2D lanthanide MOFs (Ln‐TCPP, Ln=Ce, Sm, Eu, Tb, Yb, TCPP=tetrakis(4‐carboxyphenyl) porphyrin) with different thickness were successfully prepared in a household microwave oven. The as‐prepared 2D Ln‐TCPP nanosheets showed thickness‐dependent photocatalytic performances towards photooxidation of 1,5‐dihydroxynaphthalene (1,5‐DHN) to synthesize juglone. Particularly, the Yb‐TCPP displayed outstanding photodynamic activity to generate O 2 − and 1 O 2 . This work not only provides fundamental insights into structure designing and property tailoring of 2D MOFs nanosheets, but also pave a new way to improve the photocatalytic performance." @default.
- W4239067438 created "2022-05-12" @default.
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- W4239067438 date "2020-01-16" @default.
- W4239067438 modified "2023-10-17" @default.
- W4239067438 title "Controllable Synthesis of Porphyrin‐Based 2D Lanthanide Metal–Organic Frameworks with Thickness‐ and Metal‐Node‐Dependent Photocatalytic Performance" @default.
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- W4239067438 doi "https://doi.org/10.1002/ange.201913748" @default.
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