FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4239096475> ?p ?o ?g. }

• W4239096475 endingPage "17" @default.
• W4239096475 startingPage "1" @default.
• W4239096475 abstract "The synthesis, structures and reactions of lanthanoid complexes with alkenes, alkynes and arenes have been reviewed. Whilst the discussion is centred on neutral π donors, including intramolecular π-arene-lanthanoid bonding, some formal [SmIII(C5Me5)2 (π-donor)−] complexes, derived from Sm(C5Me5)2 and neutral π donors, have been included, especially examples which readily dissociate into the reactants. Metalcarbon bond lengths for lanthanoid(II or III) complexes have been conveniently analysed and compared by subtraction of the appropriate lanthanoid ionic radius for the formal coordination number. Derived values in the approximate range 1.70–2.10 Å are typical, with higher values often associated with intramolecular π-arene-Ln coordination or dimerization through intermolecular π-arene-Ln bonding. Lower values, 1.40–1.70 Å, can carry implications of charge transfer, e.g. LnIIL0 → LnIII(L)−1 or may be partly a geometric consequence of other bonding in the molecule. The significantly covalent arene-lanthanoid(0) complexes have stronger bonding than in Ln(II or III)-(π donor) derivatives and occupy a unique place in organolanthanoid chemistry." @default.
• W4239096475 created "2022-05-12" @default.
• W4239096475 creator A5012979278 @default.
• W4239096475 creator A5078590602 @default.
• W4239096475 date "1996-04-01" @default.
• W4239096475 modified "2023-09-27" @default.
• W4239096475 title "Complexes of lanthanoids with neutral π donor ligands" @default.
• W4239096475 cites W1595392362 @default.
• W4239096475 cites W1965710422 @default.
• W4239096475 cites W1968261992 @default.
• W4239096475 cites W1968296000 @default.
• W4239096475 cites W1972412451 @default.
• W4239096475 cites W1975980833 @default.
• W4239096475 cites W1979029568 @default.
• W4239096475 cites W1979849043 @default.
• W4239096475 cites W1982082032 @default.
• W4239096475 cites W1990024898 @default.
• W4239096475 cites W1992721461 @default.
• W4239096475 cites W1994015921 @default.
• W4239096475 cites W1996287869 @default.
• W4239096475 cites W1996988318 @default.
• W4239096475 cites W1997658559 @default.
• W4239096475 cites W1998454702 @default.
• W4239096475 cites W1998568680 @default.
• W4239096475 cites W2001029990 @default.
• W4239096475 cites W2001889053 @default.
• W4239096475 cites W2007163158 @default.
• W4239096475 cites W2007441735 @default.
• W4239096475 cites W2007845610 @default.
• W4239096475 cites W2011095988 @default.
• W4239096475 cites W2014151816 @default.
• W4239096475 cites W2017822547 @default.
• W4239096475 cites W2019864172 @default.
• W4239096475 cites W2021571036 @default.
• W4239096475 cites W2023456819 @default.
• W4239096475 cites W2024490643 @default.
• W4239096475 cites W2025686423 @default.
• W4239096475 cites W2030958085 @default.
• W4239096475 cites W2033050068 @default.
• W4239096475 cites W2033660419 @default.
• W4239096475 cites W2033715439 @default.
• W4239096475 cites W2036161907 @default.
• W4239096475 cites W2038390977 @default.
• W4239096475 cites W2039008162 @default.
• W4239096475 cites W2039055696 @default.
• W4239096475 cites W2044464054 @default.
• W4239096475 cites W2045605479 @default.
• W4239096475 cites W2045922196 @default.
• W4239096475 cites W2059603559 @default.
• W4239096475 cites W2059953115 @default.
• W4239096475 cites W2061677431 @default.
• W4239096475 cites W2068784933 @default.
• W4239096475 cites W2071922234 @default.
• W4239096475 cites W2073604676 @default.
• W4239096475 cites W2074440834 @default.
• W4239096475 cites W2078270852 @default.
• W4239096475 cites W2084461308 @default.
• W4239096475 cites W2087571083 @default.
• W4239096475 cites W2088779491 @default.
• W4239096475 cites W2091085928 @default.
• W4239096475 cites W2093667450 @default.
• W4239096475 cites W2109895579 @default.
• W4239096475 cites W2112010031 @default.
• W4239096475 cites W2167590372 @default.
• W4239096475 cites W2274962701 @default.
• W4239096475 cites W2316023961 @default.
• W4239096475 cites W2329559897 @default.
• W4239096475 cites W2584639363 @default.
• W4239096475 cites W274065896 @default.
• W4239096475 cites W2950749413 @default.
• W4239096475 cites W2950955016 @default.
• W4239096475 cites W2951141724 @default.
• W4239096475 cites W2951382963 @default.
• W4239096475 cites W2953008741 @default.
• W4239096475 cites W3033383844 @default.
• W4239096475 cites W4205513757 @default.
• W4239096475 cites W4211135770 @default.
• W4239096475 cites W4254345951 @default.
• W4239096475 doi "https://doi.org/10.1016/0022-328x(96)81424-0" @default.
• W4239096475 hasPublicationYear "1996" @default.
• W4239096475 type Work @default.
• W4239096475 citedByCount "50" @default.
• W4239096475 countsByYear W42390964752012 @default.
• W4239096475 countsByYear W42390964752013 @default.
• W4239096475 countsByYear W42390964752014 @default.
• W4239096475 countsByYear W42390964752015 @default.
• W4239096475 countsByYear W42390964752021 @default.
• W4239096475 countsByYear W42390964752022 @default.
• W4239096475 crossrefType "journal-article" @default.
• W4239096475 hasAuthorship W4239096475A5012979278 @default.
• W4239096475 hasAuthorship W4239096475A5078590602 @default.
• W4239096475 hasConcept C145148216 @default.
• W4239096475 hasConcept C166950319 @default.
• W4239096475 hasConcept C178790620 @default.
• W4239096475 hasConcept C180577832 @default.
• W4239096475 hasConcept C185592680 @default.
• W4239096475 hasConcept C201770740 @default.
• W4239096475 hasConcept C32909587 @default.

• next