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- W4239204069 abstract "Die lange vernachlässigte Fähigkeit von Isoxazolen, α-Kationen extrem gut zu stabilisieren, wird genutzt, um angulare Substituenten, wie sie in Polyketid-abgeleiteten polycyclischen Naturstoffen, z. B. 1, gefunden werden, gezielt einzuführen. In einem zweistufigen Prozess schließt sich an die stereoselektive Addition eines Nucleophils an das Ketol 2 eine regio- und stereospezifische Pinakol-Umlagerung an. Bn=Benzyl; R=Allyl, Aryl, Heteroaryl, Vinyl. Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2001/2007/z605138_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article." @default.
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- W4239204069 date "2007-04-23" @default.
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- W4239204069 title "Isoxazole-Directed Pinacol Rearrangement: Stereocontrolled Approach to Angular Stereogenic Centers" @default.
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- W4239204069 doi "https://doi.org/10.1002/ange.200605138" @default.
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