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- W4239360237 abstract "Silicon-containing divinyl ether monomers were synthesized by the addition reaction of glycidyl vinyl ether (1) with various silyl dichlorides using tetra-n-butylammonium bromide (TBAB) as a catalyst. The reaction of 1 with diphenyl dichlorosilane gave bis-[1-(chloromethyl)-2-(vinyloxy)-ethyl]diphenyl silane (3a) in 89% yield. Polycondensations of 3a with terephthalic acid were also carried out using 1,8-Diazabicyclo[5.4.0]-7-undecene (DBU) to afford silicon-containing polyfunctional vinyl ether oligomers (5). A multifunctional Si-monomer with both vinyl ether and methacrylate groups (7) was prepared by the reaction of 3a with potassium methacrylate using TBAB as a phase transfer catalyst. Photoinitiated cationic polymerizations of these vinyl ether compounds proceeded rapidly using the sulfonium salt, bis-[4-(diphenyl-sulfonio)phenyl]sulfide-bis-hexafluorophoshate (DPSP), as the cationic photoinitiator in neat mixtures upon UV irradiation. Multifunctional monomer 7 with both vinyl ether and methacrylate groups showed “hybrid curing properties” using both DPSP and the radical photoinitiator, 2,4,6-trimethylbenzoyl diphenylphoshine oxide (TPO). © 1997 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 35: 3217–3225, 1997" @default.
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- W4239360237 date "1997-11-15" @default.
- W4239360237 modified "2023-09-23" @default.
- W4239360237 title "Synthesis of silicon‐containing vinyl ether monomers and oligomers and their photoinitiated polymerization" @default.
- W4239360237 doi "https://doi.org/10.1002/(sici)1099-0518(19971115)35:15<3217::aid-pola14>3.3.co;2-x" @default.
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